Techniques in Inorganic Chemistry

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Techniques in Inorganic Chemistry
English | 219 pages | ISBN-10: 1439815143 | PDF | 5.82 MB

Inorganic chemistry will continue to generate much current interest because array of applications, which range from materials to biology and medicine. Techniques in Inorganic Chemistry assembles an amount of articles from international professionals who describe modern methods utilised by research students and chemists for checking properties and structures of inorganic chemicals.

Crystallography and diffraction methods

The book begins by examining developments in small-molecule x-ray crystallography. It identifies some of the major advances, discusses current attitudes toward crystallography as well as uses, and considers challenges and prospective buyers. It then examines how ab initio x-ray powder diffraction (XRPD) methods are utilized to determine structure, with discussions on metal pyrazolates, metal imidazolates, and metal pyrimidinolates. This is followed by a description of single crystal neutron diffraction, a strong structural technique. The text highlights exactly what do presently be achieved in neutron diffraction and discusses future applications of neutron scattering.

Quantum chemistry

Reflecting the recognition of density functional calculations, the ebook includes a chapter that is targeted on quantum chemistry. It examines the latest computational techniques and describes how these techniques can be applied to unravel a wide range of real-world problems encountered within the realm of inorganic chemistry and specifically in transition metal chemistry. It also explains the intelligent use of quantum chemical means of the determination of molecular structure, reactivity, and spectra of coordination and organometallic compounds.

Spectroscopy

Lastly, the words explores important spectroscopic approaches. It first describes intermolecular nuclear Overhauser effect (NOE) NMR experiments and diffusion experiments, offering examples that report theoretical aspects of the methodology. The final chapter summarizes recent experimental and theoretical work with pressure effects on the d-d and luminescence spectra of transition metal complexes.

Derived from select articles in Comments on Inorganic Chemistry, this volume supplies a solid background in the selection of techniques available in the researcher's toolkit.

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